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1. Wood biomass as a fuel |
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Material for 5EURES Training sessions. Page compiled by Markus Huhtinen, NCP, Finland.
The sources of information: Savolainen
Berggren (editors): Puhakka et. al.:
Hakelämmitysopas Kärkkäinen: Puutiede. Hämeenlinna 1985 Hakkila: Puun ja puutavaran ominaisuuksia, Tapion Taskukirja, 19. painos Helsinki 1993 Pohjonen: Puu energialähteenä. Tapion Taskukirja, 22. uudistettu painos, Helsinki 1994 Wilen et al: Biomass feedstock analyses, VTT Publication 282, Espoo 1996 Nurmi : Heating values of whole-tree biomass in young forests in Finland. Acta Forestalia Fennica 236. Tampere 1993
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1.1 Chemical composition of wood The main components of wood cells are cellulose, hemicellulose and lignin, forming some 99 % of the wood material. Cellulose and hemicellulose are formed by long chains of carbohydrates, whereas lignin is a complicated component of polymeric phenolics. Lignin is rich in carbon and hydrogen, which are the main heat producing elements. Thus it's calorific value is higher than that of cellulose and hemicellulose (carbohydrates).Wood and bark also contain so-called extractives, such as terpenes, fats and phenols. The amount of wood extractives is relatively small compared to the amount of extractives from bark and foliage. The nitrogen (N) content of wood is about 0,75 %, varying somewhat from one tree species to another. For example, nitrogen-fixing alder (alnus sp.) contains twice as much nitrogen as most coniferous trees. Wood has practically no sulphur (S) at all, as it's share in wood is 0,05 % at the highest (Pohjonen 1994). Compared to many other fuels, the wood has a relatively low carbon content (some 50 % of dry weight) and high oxygen content (some 40 %), which leads to relatively low heating value per dry weight. Table 1.1: Average chemical contents of wood fuels
Table 1.2 Heating values of some fuels
1.2 Properties of wood fuels The most important fuel properties are:
The moisture content has big effect to the net calorific value reached at the burning process. The moisture content is stated as weight % of the wet base (as received). Moisture content influences significantly the net calorific heating value. Vaporising water requires energy from the burning process (0.7 kWh per a kilogram of water), thus reducing the net heating value of the fuel (Figure 1).
The moisture content of wood fuels varies from 20 to 65 % and is influenced among other things by:
Basic density (kg/m3) indicates the relationship of dry mass to solid volume measure (or how much dry wood weighs per a solid measure of wood). Solid volume content of fuel is needed when so called bulk measure of fuel is converted into solid measure. Bulk density of the Northern European woody biomasses is in the range of 200-350 kg per loose m3. Table1.2. The bulk density of Northern European woody biomasses (Wilen et al. 1996).
The particle size of wood fuels varies from sawdust-like needle and bark material to sticks of wood and branch pieces. Especially the forest chip quality is very variable. The more stemwood the raw material contains, the more even the particle size distribution will be. Heating value of wood fuels It is important to recognize different terms of heating values: Calorimetric value = Amount of energy created when one kg of absolutely dry wood is burned and all water created in burning process is condensed (HHV, combustion heat). Dry wood effective heating value = Amount of energy created when one kg of absolutely dry wood is burned and water created in the burning process vaporizes (LHV). Effective heating value = Amount of energy created when one kg of moist wood is burned and water content of the fuel and water created in burning process vaporize (LHV. The calorific heating value of wood does not vary much from one tree species to another (18.7-21.9 MJ/kg), but is slightly huigher in coniferous species than in broadleaved or deciduous tree species. Similarly, there are some difference between the effective heating values of Nordic tree species. The conifers have slightly higher values than deciduous trees due to their higher lignin and resin contents. Table 1.3. Stemwood qualities (Hakkila 1978, Nurmi 1993)
Heating values per volume unit The heating values are normally given per kilogram of solid wood. For wood the value range is 18.5-21.0 MJ/kg. However, in forestry it is quite normal to measure the amount of stemwood as solid cubic meters (m3). The denser species naturally have higher heating value per m3 of solid stemwood (tables 1 and 2). Table 1.4. Effective heating values of tree species, MJ/m3.
Ash content and properties Ash content means the amount of solid wastes after complete burning process of the fuel. It can be expressed as weight % of the dry base or as a weight % of the as received (ar) material. High ash content of the fuel generally reduces it's heating value. The ash content of wood biomasses ranges from 0.08 to 2.3 % Amount of volatiles The combustibles of solid fuels can be shared into two groups: volatile matters and components combusting as solid carbon. The share of volatile matters wood is typically high, 80 % of the energy originating in the combustion of volatile matters. Results of proximate and ultimate analysis In the so-called proximate analysis of wood fuels, such properties as solid carbon, volatile materials and moisture contents are defined. In ultimate analysis one defines the share of most important elements such as C, H, O, N, S, Cl, F and Br. 1.3 Tree components The tree biomass can be dividide into different components, depending mainly on the minimum diameter of industrially usable logs. If we assume that the minimum top diameter of industrially usable logs is 5 cm we can use following figures (Hakkila 1983): Table1.5. Stemwood, treetops and branches biomass, % of the total harvest.
Heating values of different tree components The bark, crown and stumps of the tree have typically somewhat higher effective heating values than the stemwood. Table 1.6. Tree component heating values
2. Wood Energy and environment
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Logging residues pile ready for chipping
Birch has high heating value per volume unit.
The Norway Spruce stand has high proportion of needles, bark and branches.
Uncommercial roundwood stored for chipping .
Branches and other logging residues have high heating value
Roadside chipper in action
Stumps are harvested at UPM logging site near Jyväskylä |
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